| MD Q-R32 | Arnaldos Serrano/Rodriguez Martinez def. Sintes Villalonga/Moragues Moltò 6-7 3-6 |
| MD Q-R32 | Araujo/Castro Garcia def. Sinicropi/Ruiz 7-6 7-6 |
| MD Q-R32 | Guichard/Luque def. Melendez Amaya/Mena 6-3 6-7 3-6 |
| MD Q-R32 | Garcia/Marti def. Aragon Herrera/Jerez Carnero 6-7 7-6 6-3 |
| MD Q-R32 | Olsson/Windahl def. Castillo Valverde/Jorge Alfaro 7-5 2-6 5-7 |
| MD Q-R32 | Tinti/Giuliani def. Nunes/Solbes 4-6 7-5 6-3 |
| MD Q-R32 | Blanque/Bergeron def. Marques Berdonce/Gonzalez 6-2 7-5 |
| MD Q-R32 | Insa Sotillo/Coello Manso def. Gil/Ramirez 3-6 4-6 |
| MD Q-R16 | Ramirez Navas/Axelsson def. Guichard/Luque 6-3 6-2 |
| MD Q-R16 | Huete Hernandez/Perino def. Insa Sotillo/Coello Manso 7-6 2-6 3-6 |
| MD Q-R16 | Bueno/Mendez def. Garcia/Marti 3-6 7-5 6-7 |
| MD Q-R16 | Olsson/Windahl def. Garcia Jimenez/Medina Murphy 4-6 6-4 4-6 |
| MD Q-R16 | Rubini/Lamperti def. Tinti/Giuliani 3-6 4-6 |
| MD Q-R16 | Fernandez Lancha/Jensen Sirvent def. Arnaldos Serrano/Rodriguez Martinez 7-6 7-6 |
| MD Q-R16 | Blanque/Bergeron def. Castaño Salguero/Suescun 7-6 6-4 |
| MD Q-R16 | Vasquez/Geens def. Araujo/Castro Garcia 6-3 6-2 |
| MD Q-QF | Blanque/Bergeron def. Vasquez/Geens 3-6 4-6 |
| MD Q-QF | Ramirez Navas/Axelsson def. Rubini/Lamperti 6-4 6-4 |
| MD Q-QF | Olsson/Windahl def. Huete Hernandez/Perino 7-6 7-6 |
| MD Q-QF | Fernandez Lancha/Jensen Sirvent def. Bueno/Mendez 6-3 3-0 0-0 0-0 |
| MD R64 | Ayats/Garcia def. Ortega/Del Castillo 2-6 6-4 6-2 |
| MD R64 | Melendez Amaya/Dominguez def. Cepero/Torre 6-7 6-2 6-3 |
| MD R64 | Cassetta/Gonzalez def. Blanque/Bergeron 6-2 6-2 |
| MD R64 | Campagnolo/Sager def. Patiniotis/Gala 4-6 6-7 |
| MD R64 | Moyano/Cabeza Teres def. Mouriño/Fernandez 6-4 6-4 |
| MD R64 | Fernandez Lancha/Jensen Sirvent def. Hernandez Alvarez/Valenzuela 7-6 6-7 5-7 |
| MD R64 | Goenaga/Hernandez Quesada def. Olsson/Windahl 6-4 6-2 |
| MD R64 | Iacovino/Di Giovanni def. Cremona/Graziotti 6-7 6-4 3-6 |
| MD R64 | Ruiz/Gil def. Rubio/Ruiz 6-3 6-2 |
| MD R64 | Deus/Deus def. Leygue/Moya 6-4 1-1 0-0 0-0 |
| MD R64 | Piotto Albornoz/Rico def. Aguirre/Alfonso 3-6 6-7 |
| MD R64 | Valdes/Collado def. Ramirez Navas/Axelsson 6-7 4-6 |
| MD R64 | Martinez/Benitez Lara def. Vilariño Gestoso/Oria 5-7 6-2 5-7 |
| MD R64 | Sánchez Chamero/Santigosa Sastre def. Munoz/Gutierrez 2-6 2-6 |
| MD R64 | Lijo/Belluati def. Abbate/Montiel Caruso 6-7 3-6 |
| MD R64 | Zapata/Jimenez Casas def. Garcia Garcia/Rico 2-6 4-6 |
| MD R32 | Huete Hernandez/Perino def. Moyano/Cabeza Teres 6-3 6-4 |
| MD R32 | Diestro/Esbri def. Sánchez Chamero/Santigosa Sastre 2-6 7-6 4-6 |
| MD R32 | Stupaczuk/Lebron def. Ayats/Garcia 6-3 6-2 |
| MD R32 | Yanguas/Nieto def. Zapata/Jimenez Casas 2-6 6-3 3-6 |
| MD R32 | Alonso/Bautista def. Melendez Amaya/Dominguez 6-2 6-3 |
| MD R32 | Ruiz/Sanchez def. Ruiz/Gil 7-5 7-6 |
| MD R32 | Bergamini/Navarro def. Cassetta/Gonzalez 5-7 3-6 |
| MD R32 | Chozas/Gutierrez def. Martinez/Benitez Lara 7-6 3-6 6-4 |
| MD R32 | Guerrero/Leal def. Goenaga/Hernandez Quesada 4-6 6-7 |
| MD R32 | Gonzalez/Sanz def. Fernandez Lancha/Jensen Sirvent 2-6 6-7 |
| MD R32 | Barahona/Garcia def. Iacovino/Di Giovanni 0-6 4-6 |
| MD R32 | Tello/Di Nenno def. Lijo/Belluati 6-3 7-6 |
| MD R32 | Coello/Tapia def. Deus/Deus 6-2 6-1 |
| MD R32 | Campagnolo/Sager def. Cardona/Augsburger 6-7 5-7 |
| MD R32 | Chingotto/Galan def. Valdes/Collado 2-6 3-6 |
| MD R32 | Jofre/Arroyo def. Piotto Albornoz/Rico 6-7 6-3 6-7 |
| MD R16 | Yanguas/Nieto def. Chozas/Gutierrez 3-6 5-7 |
| MD R16 | Coello/Tapia def. Diestro/Esbri 6-3 6-2 |
| MD R16 | Chingotto/Galan def. Huete Hernandez/Perino 0-6 2-6 |
| MD R16 | Stupaczuk/Lebron def. Barahona/Garcia 6-3 4-6 6-3 |
| MD R16 | Bergamini/Navarro def. Alonso/Bautista 6-7 6-3 1-6 |
| MD R16 | Guerrero/Leal def. Tello/Di Nenno 6-7 2-6 |
| MD R16 | Jofre/Arroyo def. Campagnolo/Sager 4-6 5-7 |
| MD R16 | Gonzalez/Sanz def. Ruiz/Sanchez 4-6 4-6 |
| MD QF | Coello/Tapia def. Bergamini/Navarro 6-4 6-2 |
| MD QF | Chingotto/Galan def. Jofre/Arroyo 6-7 3-6 |
| MD QF | Stupaczuk/Lebron def. Gonzalez/Sanz 6-3 6-7 7-6 |
| MD QF | Guerrero/Leal def. Yanguas/Nieto 5-7 6-3 7-6 |
| MD SF | Coello/Tapia def. Guerrero/Leal 6-7 6-2 6-2 |
| MD SF | Chingotto/Galan def. Stupaczuk/Lebron 6-4 6-7 2-6 |
| MD F | Chingotto/Galan def. Coello/Tapia 3-6 5-7 |
| WD Q-R16 | Martinez Sanjuan/Dominguez Gracia def. Lucendo Millan/Blanco Rojo 6-7 0-6 |
| WD Q-R16 | Lopez Lopez/Lopez Moral def. Piltcher/Ortiz Gasco 6-3 3-6 6-7 |
| WD Q-R16 | Koek/Weterings def. Serrano Gonzalez/Ramme Coellar 6-2 7-5 |
| WD Q-R16 | Pujals Perez/Valenzuela def. Portillo Perez/Fernandez Lopez 3-6 3-6 |
| WD Q-R16 | Aima/Rosi def. Schuck Silva/Ribeiro 6-7 1-6 |
| WD Q-R16 | Garcia Trella/Lopez Diaz def. Baldi/Gibson 7-6 6-4 |
| WD Q-R16 | Navarro Björk/Touly def. Montesi/Castillo Velarde 6-3 6-4 |
| WD Q-R16 | Vano/Peralta Exposito def. Vivancos/Clasca Vidiella 3-6 4-6 |
| WD Q-QF | Pujals Perez/Valenzuela def. Navarro Björk/Touly 2-6 5-7 |
| WD Q-QF | Martinez Sanjuan/Dominguez Gracia def. Garcia Trella/Lopez Diaz 3-6 4-6 |
| WD Q-QF | Lopez Lopez/Lopez Moral def. Koek/Weterings 4-6 6-2 3-6 |
| WD Q-QF | Vano/Peralta Exposito def. Aima/Rosi 4-6 2-6 |
| WD R64 | Bellver Fructuoso/Rodriguez Abajo def. Errani/Dal Pozzo 6-7 5-7 |
| WD R64 | Arruabarrena/Bidahorria def. Cañellas Rodero/Soriano Perez 6-3 6-1 |
| WD R64 | Martinez Fortun/Manquillo Alarza def. Pappacena/Parmigiani 6-1 6-3 |
| WD R64 | Perez Ortiz/Borrero def. Martinez Sanjuan/Dominguez Gracia 6-2 6-3 |
| WD R64 | Polo Bautista/Aguilar Carrillo def. Perez Momha/Varo Ramos 7-6 4-6 6-7 |
| WD R64 | Velasco Postiguillo/Canovas Paredes def. Saiz Vallejo/Lobo 7-6 4-6 6-7 |
| WD R64 | Nogueira/Fassio Goyeneche def. Fassio Goyeneche/Gomez Rivas 6-2 6-1 |
| WD R64 | Las Heras/Marchetti def. Casali/Gallardo Salvado 4-6 5-7 |
| WD R64 | Barrera De La Fuente/Caparros Maldonado def. Montes Cabruja/Arellano Navarro 6-3 6-7 6-3 |
| WD R64 | Pujals Perez/Valenzuela def. Vano/Peralta Exposito 6-1 1-6 6-3 |
| WD R64 | Lopez Lopez/Lopez Moral def. Lujan Rodriguez/Godallier 7-5 1-6 7-6 |
| WD R64 | Merino Saez/Navarro lopez-Barajas def. Ruiz Soto/Mesa Salazar 5-7 6-4 6-3 |
| WD R32 | Martinez Gomez/Marrero def. Las Heras/Marchetti 6-4 6-4 |
| WD R32 | Barrera De La Fuente/Caparros Maldonado def. Orsi/Rodriguez 7-6 1-6 3-6 |
| WD R32 | Icardo Alcorisa/Jensen def. Perez Ortiz/Borrero 6-3 6-4 |
| WD R32 | Talavan/Sharifova def. Pujals Perez/Valenzuela 4-6 2-6 |
| WD R32 | Ortega Gallego/Alonso De Villa def. Martinez Fortun/Manquillo Alarza 1-6 1-6 |
| WD R32 | Sainz Pelegri/Llaguno Zielinski def. Bellver Fructuoso/Rodriguez Abajo 6-2 6-2 |
| WD R32 | Guinart España/Iglesias Segador def. Nogueira/Fassio Goyeneche 4-6 4-6 |
| WD R32 | Caldera Sanchez/Goenaga Garcia def. Velasco Postiguillo/Canovas Paredes 1-6 3-6 |
| WD R32 | Eugenio Barrera/Riera def. Arruabarrena/Bidahorria 6-1 6-3 |
| WD R32 | Osoro Ulrich/Calvo Santamaria def. Lopez Lopez/Lopez Moral 0-6 1-6 |
| WD R32 | Collombon/Martinez def. Polo Bautista/Aguilar Carrillo 1-6 7-6 6-2 |
| WD R32 | Virseda/Salazar Bengoechea def. Merino Saez/Navarro lopez-Barajas 4-6 2-6 |
| WD R16 | Triay Pons/Brea Senesi def. Eugenio Barrera/Riera 0-6 0-6 |
| WD R16 | Fernandez Sanchez/Gonzalez Fernandez def. Martinez Gomez/Marrero 3-6 0-6 |
| WD R16 | Sanchez Fallada/Josemaria Martin def. Osoro Ulrich/Calvo Santamaria 6-4 6-2 |
| WD R16 | Ortega Gallego/Alonso De Villa def. Collombon/Martinez 3-6 4-6 |
| WD R16 | Guinart España/Iglesias Segador def. Araujo/Ustero Prieto 6-7 6-4 1-6 |
| WD R16 | Barrera De La Fuente/Caparros Maldonado def. Virseda/Salazar Bengoechea 6-1 7-5 |
| WD R16 | Icardo Alcorisa/Jensen def. Talavan/Sharifova 6-4 6-3 |
| WD R16 | Caldera Sanchez/Goenaga Garcia def. Sainz Pelegri/Llaguno Zielinski 6-7 3-6 |
| WD QF | Fernandez Sanchez/Gonzalez Fernandez def. Caldera Sanchez/Goenaga Garcia 2-6 3-6 |
| WD QF | Sanchez Fallada/Josemaria Martin def. Ortega Gallego/Alonso De Villa 7-6 5-7 6-2 |
| WD QF | Guinart España/Iglesias Segador def. Barrera De La Fuente/Caparros Maldonado 6-3 6-3 |
| WD QF | Triay Pons/Brea Senesi def. Icardo Alcorisa/Jensen 3-6 1-6 |
| WD SF | Triay Pons/Brea Senesi def. Guinart España/Iglesias Segador 3-6 1-6 |
| WD SF | Sanchez Fallada/Josemaria Martin def. Fernandez Sanchez/Gonzalez Fernandez 7-6 6-3 |
| WD F | Triay Pons/Brea Senesi def. Sanchez Fallada/Josemaria Martin 4-6 4-6 |