| MD Q-R32 | Zamora Perez/Mendez def. Dorta Diaz/Castro Garcia 1-6 1-6 |
| MD Q-R32 | Figuerola Santiago/Belmont Pastor def. Guerrero Escarcena/Varo Ramos 7-6 6-3 |
| MD Q-R32 | Graziotti/Iacovino def. Arnaldos Serrano/Garcia Rubio 4-6 1-6 |
| MD Q-R32 | Gonzalez Blanco/Aliaga def. Nunes/Solano Marmolejo 2-6 2-6 |
| MD Q-R32 | Perez Arbona/Rodriguez def. Behbehani/Mena 6-2 7-6 |
| MD Q-R32 | Arija Ochoa De Alda/Moyano def. Sanchez Vicente/Morales Domenech 3-6 4-6 |
| MD Q-R32 | Guichard/Luque def. Shams/Moreno Carrasco 6-2 6-4 |
| MD Q-R32 | Fuster/Solbes def. Joris/Vives 0-0 |
| MD Q-R16 | Zamora Perez/Mendez def. Geens/Moragues Moltò 2-6 5-7 |
| MD Q-R16 | Marques Berdonce/Axelsson def. Perez Arbona/Rodriguez 3-6 1-6 |
| MD Q-R16 | Melendez Amaya/Melendez Amaya def. Guichard/Luque 4-6 6-3 2-6 |
| MD Q-R16 | Abbate/Castaño Salguero def. Fuster/Solbes 2-6 3-6 |
| MD Q-R16 | Jerez Carnero/Lamperti def. Arija Ochoa De Alda/Moyano 1-6 5-7 |
| MD Q-R16 | Graziotti/Iacovino def. Gil/Rico 7-6 4-6 4-6 |
| MD Q-R16 | Capra/Goñi Lacabe def. Gonzalez Blanco/Aliaga 6-3 6-2 |
| MD Q-R16 | Ortega/Huete Hernandez def. Figuerola Santiago/Belmont Pastor 7-5 6-2 |
| MD Q-QF | Capra/Goñi Lacabe def. Marques Berdonce/Axelsson 6-2 6-4 |
| MD Q-QF | Abbate/Castaño Salguero def. Graziotti/Iacovino 6-7 4-6 |
| MD Q-QF | Zamora Perez/Mendez def. Jerez Carnero/Lamperti 6-2 6-4 |
| MD Q-QF | Melendez Amaya/Melendez Amaya def. Ortega/Huete Hernandez 2-6 4-6 |
| MD R64 | Melendez Amaya/Melendez Amaya def. Valenzuela/Mouriño 6-1 4-6 6-4 |
| MD R64 | Goenaga/Hernandez Quesada def. Nawaf/Nawaf 6-2 6-1 |
| MD R64 | Rubio/Ruiz def. Santigosa Sastre/Sintes Villalonga 6-7 2-6 |
| MD R64 | Perino/Piotto Albornoz def. Deus/Deus 4-6 6-3 4-6 |
| MD R64 | Martinez/Dominguez def. Valdes/Gutierrez 0-6 3-6 |
| MD R64 | Rodriguez Martinez/Rubini def. Alansari/Chiostri 6-3 6-4 |
| MD R64 | Cassetta/Gonzalez def. Alawadhi/Marcos 2-6 3-6 |
| MD R64 | Garcia/Gala def. Fernandez/Del Castillo 7-5 6-4 |
| MD R64 | Capra/Goñi Lacabe def. Patiniotis/Moya 6-3 6-1 |
| MD R64 | Sanchez/Gil def. Sans/Quilez 3-6 6-2 6-4 |
| MD R64 | Sanchez Blasco/Jimenez Casas def. Montiel Caruso/Belluati 2-6 6-3 6-2 |
| MD R64 | Lijo/Arce Simo def. Zapata/Cabeza Teres 6-0 5-0 0-0 0-0 |
| MD R64 | Zamora Perez/Mendez def. Sánchez Chamero/Jensen Sirvent 7-6 6-4 |
| MD R64 | Diestro/Ruiz def. Garcia Garcia/Oria 5-7 6-3 5-1 0-0 0-0 |
| MD R64 | Torre/Cepero def. Fernandez Lancha/Sager 6-2 7-6 |
| MD R64 | Collado/Hernandez Alvarez def. Abbate/Castaño Salguero 6-2 6-3 |
| MD R32 | Rodriguez Martinez/Rubini def. Libaak/Bautista 6-4 3-6 6-3 |
| MD R32 | Ruiz/Esbri def. Perino/Piotto Albornoz 6-7 4-6 |
| MD R32 | Garcia/Gala def. Di Nenno/Augsburger 7-6 6-7 6-7 |
| MD R32 | Gonzalez/Guerrero def. Melendez Amaya/Melendez Amaya 2-6 1-6 |
| MD R32 | Garrido/Campagnolo def. Martinez/Dominguez 6-1 6-2 |
| MD R32 | Coello/Tapia def. Capra/Goñi Lacabe 6-1 7-5 |
| MD R32 | Nieto/Yanguas def. Torre/Cepero 1-6 6-7 |
| MD R32 | Gutierrez/Alfonso def. Cassetta/Gonzalez 6-7 6-2 6-1 |
| MD R32 | Lebron/Stupaczuk def. Lijo/Arce Simo 6-4 6-2 |
| MD R32 | Collado/Hernandez Alvarez def. Jofre/Arroyo 6-1 6-4 |
| MD R32 | Sanz/Navarro def. Diestro/Ruiz 4-6 2-6 |
| MD R32 | Alonso/Tello def. Zamora Perez/Mendez 6-4 6-4 |
| MD R32 | Sanchez Blasco/Jimenez Casas def. Leal/Bergamini 4-6 2-6 |
| MD R32 | Aguirre/Chozas def. Rubio/Ruiz 5-7 2-6 |
| MD R32 | Goenaga/Hernandez Quesada def. Garcia/Barahona 5-7 6-1 4-6 |
| MD R32 | Chingotto/Galan def. Sanchez/Gil 1-6 0-6 |
| MD R16 | Gonzalez/Guerrero def. Garrido/Campagnolo 7-6 2-6 2-6 |
| MD R16 | Garcia/Gala def. Rodriguez Martinez/Rubini 6-4 7-6 |
| MD R16 | Nieto/Yanguas def. Gutierrez/Alfonso 6-7 3-6 |
| MD R16 | Coello/Tapia def. Ruiz/Esbri 6-3 6-1 |
| MD R16 | Chingotto/Galan def. Goenaga/Hernandez Quesada 2-6 4-6 |
| MD R16 | Aguirre/Chozas def. Sanchez Blasco/Jimenez Casas 5-7 3-6 |
| MD R16 | Lebron/Stupaczuk def. Collado/Hernandez Alvarez 6-0 6-2 |
| MD R16 | Sanz/Navarro def. Alonso/Tello 4-6 3-6 |
| MD QF | Chingotto/Galan def. Aguirre/Chozas 2-6 4-6 |
| MD QF | Coello/Tapia def. Gonzalez/Guerrero 6-4 4-6 6-3 |
| MD QF | Nieto/Yanguas def. Garcia/Gala 2-6 2-6 |
| MD QF | Sanz/Navarro def. Lebron/Stupaczuk 2-6 6-4 4-6 |
| MD SF | Coello/Tapia def. Nieto/Yanguas 6-4 7-6 |
| MD SF | Chingotto/Galan def. Sanz/Navarro 4-6 2-6 |
| MD F | Chingotto/Galan def. Coello/Tapia 6-2 5-7 2-6 |
| WD Q-R16 | Varo Ramos/Fernandez Lopez def. Binwathlan/Repcikova 0-6 0-6 |
| WD Q-R16 | Lopez Diaz/Lopez Lopez def. Metwally/Azcoitia Mazo 0-6 1-6 |
| WD Q-R16 | Koek/Kurz def. Tokumoto/Tsukamoto 6-1 6-2 |
| WD Q-R16 | Ortiz Gasco/Fassio Goyeneche def. Hassan/Sanchez Vera 6-0 6-1 |
| WD Q-R16 | Perez Momha/Vano def. Ordoñez Romero/Lucendo Millan 6-2 6-0 |
| WD Q-R16 | Peralta Exposito/Touly def. Luttikhuis/Hemmes 4-6 3-6 |
| WD Q-R16 | Casali/Cañellas Rodero def. Fito Fernandez/Araus Lopez 6-3 6-1 |
| WD Q-R16 | Piltcher/Valenzuela def. Portillo Perez/Perez Parra 2-6 2-6 |
| WD Q-QF | Lopez Diaz/Lopez Lopez def. Koek/Kurz 6-3 1-6 5-7 |
| WD Q-QF | Piltcher/Valenzuela def. Perez Momha/Vano 2-6 7-5 6-6 0-0 0-0 |
| WD Q-QF | Casali/Cañellas Rodero def. Peralta Exposito/Touly 6-4 2-6 6-4 |
| WD Q-QF | Ortiz Gasco/Fassio Goyeneche def. Varo Ramos/Fernandez Lopez 6-0 6-7 7-5 |
| WD R32 | Canovas Paredes/Rodriguez Abajo def. Osoro Ulrich/Iglesias Segador 6-4 4-6 6-2 |
| WD R32 | Caldera Sanchez/Goenaga Garcia def. Sharifova/Lobo 2-6 3-6 |
| WD R32 | Sainz Pelegri/Eugenio Barrera def. Collombon/Montes Cabruja 5-7 5-7 |
| WD R32 | Ortega Gallego/Icardo Alcorisa def. Marchetti/Godallier 3-6 4-6 |
| WD R32 | Guinart España/Virseda def. Carnicero Martin/Martinez Fortun 6-3 6-2 |
| WD R32 | Fassio Goyeneche/Llaguno Zielinski def. Navarro Björk/Merino Saez 6-2 6-2 |
| WD R32 | Aguilar Carrillo/Navarro lopez-Barajas def. Riera/Nogueira 2-6 4-6 |
| WD R32 | Salazar Bengoechea/Calvo Santamaria def. Arruabarrena/Bidahorria 6-0 6-3 |
| WD R32 | Castello Lopez/Rufo Ortiz def. Mesa Salazar/Ruiz Soto 6-0 6-4 |
| WD R32 | Alonso De Villa/Jensen def. Casali/Cañellas Rodero 0-6 2-6 |
| WD R32 | Orsi/Martinez def. Lujan Rodriguez/Manquillo Alarza 2-6 7-6 5-7 |
| WD R32 | Barrera De La Fuente/Velasco Postiguillo def. Lopez Moral/Garcia Trella 6-2 6-1 |
| WD R16 | Ortega Gallego/Icardo Alcorisa def. Aguilar Carrillo/Navarro lopez-Barajas 0-6 1-6 |
| WD R16 | Salazar Bengoechea/Calvo Santamaria def. Sainz Pelegri/Eugenio Barrera 6-0 6-2 |
| WD R16 | Triay Pons/Brea Senesi def. Caldera Sanchez/Goenaga Garcia 6-2 6-2 |
| WD R16 | Alonso De Villa/Jensen def. Castello Lopez/Rufo Ortiz 3-6 2-6 |
| WD R16 | Guinart España/Virseda def. Orsi/Martinez 6-3 6-1 |
| WD R16 | Ustero Prieto/Araujo def. Barrera De La Fuente/Velasco Postiguillo 2-6 3-6 |
| WD R16 | Sanchez Fallada/Josemaria Martin def. Fassio Goyeneche/Llaguno Zielinski 6-2 5-7 3-6 |
| WD R16 | Fernandez Sanchez/Gonzalez Fernandez def. Canovas Paredes/Rodriguez Abajo 6-4 7-6 |
| WD QF | Sanchez Fallada/Josemaria Martin def. Guinart España/Virseda 4-6 3-6 |
| WD QF | Triay Pons/Brea Senesi def. Alonso De Villa/Jensen 6-2 6-1 |
| WD QF | Ustero Prieto/Araujo def. Salazar Bengoechea/Calvo Santamaria 4-6 7-5 2-6 |
| WD QF | Ortega Gallego/Icardo Alcorisa def. Fernandez Sanchez/Gonzalez Fernandez 4-6 1-6 |
| WD SF | Triay Pons/Brea Senesi def. Ustero Prieto/Araujo 6-1 7-6 |
| WD SF | Sanchez Fallada/Josemaria Martin def. Ortega Gallego/Icardo Alcorisa 6-7 2-6 |
| WD F | Sanchez Fallada/Josemaria Martin def. Triay Pons/Brea Senesi 3-6 3-6 |