| MD Q-R16 | Marques Berdonce/Sintes Villalonga def. Arnaldos Serrano/Mendez 2-6 6-2 4-6 |
| WD Q-QF | Polo Bautista/Aguilar Carrillo def. Lopez Diaz/Garcia Trella 6-7 2-6 |
| MD Q-R16 | Gutierrez/Valdes def. Guichard/Dorta Diaz 7-6 6-3 |
| MD Q-R32 | Jensen Sirvent/Dal Bianco def. Belmont Pastor/Tur Checa 7-6 6-2 |
| MD Q-R16 | Rodriguez Martinez/Rubini def. Miñano Ortinez/Mena 3-6 6-4 3-6 |
| MD R32 | Alonso/Tello def. Gutierrez/Nuñez 1-6 3-6 |
| WD R16 | Jensen/Alonso De Villa def. Velasco Postiguillo/Eugenio Barrera 6-4 6-2 |
| MD Q-R16 | Quilez/Sans def. Graziotti/Iacovino 6-3 7-5 |
| WD R16 | Guinart España/Virseda def. Martinez Fortun/Montes Cabruja 2-6 3-6 |
| WD R32 | Velasco Postiguillo/Eugenio Barrera def. Barrera De La Fuente/Caparros Maldonado 4-6 6-0 6-2 |
| WD R32 | Martinez Fortun/Montes Cabruja def. Koek/Weterings 2-6 2-6 |
| MD R64 | Rico/Sager def. Abbate/Cassetta 6-4 6-3 |
| MD R64 | Marques Berdonce/Sintes Villalonga def. Torre/Moragues Moltò 5-7 4-6 |
| MD R64 | Rodriguez Martinez/Rubini def. Deus/Deus 6-7 7-5 6-2 |
| MD R64 | Rubio/Ruiz def. Perino/Piotto Albornoz 3-6 5-7 |
| MD R64 | Dominguez/Martinez def. Richters/Roper 0-6 2-6 |
| MD R64 | Gutierrez/Nuñez def. Prins/De Kroon 3-6 6-4 7-5 |
| MD R64 | Quilez/Sans def. Santigosa Sastre/Axelsson 4-6 4-6 |
| MD R16 | Leal/Bergamini def. Marques Berdonce/Sintes Villalonga 6-3 6-4 |
| MD QF | Nieto/Yanguas def. Sanz/Navarro 3-6 6-1 3-6 |
| MD QF | Stupaczuk/Lebron def. Gutierrez/Alfonso 6-1 7-6 |
| MD R16 | Nieto/Yanguas def. Esbri/Diestro 6-7 1-6 |
| MD R16 | Gutierrez/Alfonso def. Di Nenno/Augsburger 3-6 6-3 7-5 |
| MD QF | Chingotto/Galan def. Leal/Bergamini 6-7 2-6 |
| MD R16 | Chingotto/Galan def. Jofre/Arroyo 5-7 4-6 |
| MD R16 | Guerrero/Gonzalez def. Mouriño/Valenzuela 3-6 4-6 |
| MD R16 | Sanz/Navarro def. Libaak/Bautista 6-2 7-6 |
| MD QF | Coello/Tapia def. Guerrero/Gonzalez 6-2 6-3 |
| MD R16 | Stupaczuk/Lebron def. Alonso/Tello 6-3 7-6 |
| WD R32 | Jensen/Alonso De Villa def. Saiz Vallejo/Talavan 6-2 6-4 |
| WD R32 | Guinart España/Virseda def. Canovas Paredes/Rodriguez Abajo 2-6 6-4 2-6 |
| WD R32 | Castello Lopez/Rufo Ortiz def. Merino Saez/Nogueira 6-1 6-1 |
| WD R32 | Ortega Gallego/Icardo Alcorisa def. Caldera Sanchez/Goenaga Garcia 7-6 6-3 |
| WD R32 | Sainz Pelegri/Llaguno Zielinski def. Collombon/Martinez 6-2 6-3 |
| WD R32 | Osoro Ulrich/Iglesias Segador def. Perez Ortiz/Borrero 2-6 3-6 |
| WD R32 | Arruabarrena/Bidahorria def. Polo Bautista/Aguilar Carrillo 4-6 6-7 |
| WD R16 | Brea Senesi/Triay Pons def. Martinez Gomez/Rodriguez 0-0 |
| WD R32 | Salazar Bengoechea/Calvo Santamaria def. Mesa Salazar/Ruiz Soto 1-6 2-6 |
| WD QF | Sanchez Fallada/Josemaria Martin def. Ortega Gallego/Icardo Alcorisa 2-6 3-6 |
| WD SF | Sanchez Fallada/Josemaria Martin def. Salazar Bengoechea/Calvo Santamaria 3-6 2-6 |
| WD SF | Brea Senesi/Triay Pons def. Jensen/Alonso De Villa 6-7 6-2 6-4 |
| WD Q-R16 | Polo Bautista/Aguilar Carrillo def. Dominguez Gracia/Martinez Sanjuan 4-6 3-6 |
| WD Q-R16 | Lopez Diaz/Garcia Trella def. Bellver Fructuoso/Cañellas Rodero 2-6 4-6 |
| WD Q-R16 | Godallier/Marchetti def. Luttikhuis/Hemmes 7-6 6-3 |
| WD Q-R16 | Martinez Fortun/Montes Cabruja def. Perez Momha/Vano 1-6 4-6 |
| WD R32 | Orsi/Fassio Goyeneche def. Sharifova/Riera 6-4 6-3 |
| MD R32 | Mouriño/Valenzuela def. Garcia/Barahona 5-7 4-6 |
| MD R64 | Esbri/Diestro def. Capra/Goñi Lacabe 4-6 7-5 0-0 0-0 0-0 |
| MD R32 | Sanz/Navarro def. Gutierrez/Valdes 7-5 6-2 |
| MD R64 | Sanchez/Gil def. Hernandez Alvarez/Collado 6-1 1-6 6-3 |
| MD R32 | Gutierrez/Alfonso def. Rodriguez Martinez/Rubini 7-6 6-3 |
| MD R64 | Patiniotis/Moya def. Arce Simo/Lijo 5-7 6-7 |
| MD Q-R16 | Abbate/Cassetta def. De Pascual/Lamperti 6-7 6-7 |
| MD R32 | Esbri/Diestro def. Ruiz/Ruiz 4-6 4-6 |
| MD R32 | Stupaczuk/Lebron def. Patiniotis/Moya 6-4 6-2 |
| MD R32 | Coello/Tapia def. Goenaga/Hernandez Quesada 6-3 6-3 |
| MD R64 | Gala/Campagnolo def. Jimenez Casas/Sanchez Blasco 7-5 6-4 |
| MD R32 | Libaak/Bautista def. Sanchez/Gil 6-1 3-6 4-6 |
| MD R32 | Nieto/Yanguas def. Gala/Campagnolo 2-6 7-6 5-7 |
| WD F | Brea Senesi/Triay Pons def. Sanchez Fallada/Josemaria Martin 6-2 3-6 6-4 |
| MD Q-R32 | Guichard/Dorta Diaz def. Blanque/Bergeron 5-7 6-7 |
| WD R16 | Arruabarrena/Bidahorria def. Luttikhuis/Hemmes 6-1 6-0 |
| WD R16 | Ustero Prieto/Araujo def. Castello Lopez/Rufo Ortiz 6-3 6-4 |
| WD QF | Salazar Bengoechea/Calvo Santamaria def. Ustero Prieto/Araujo 3-6 4-6 |
| WD R16 | Ortega Gallego/Icardo Alcorisa def. Osoro Ulrich/Iglesias Segador 6-4 6-4 |
| MD Q-R32 | Geens/Jerez Carnero def. Garcia Jimenez/Martinez Sanchis 6-3 6-1 |
| WD R16 | Sanchez Fallada/Josemaria Martin def. Sainz Pelegri/Llaguno Zielinski 4-6 1-6 |
| WD R16 | Salazar Bengoechea/Calvo Santamaria def. Orsi/Fassio Goyeneche 3-6 4-6 |
| WD QF | Brea Senesi/Triay Pons def. Guinart España/Virseda 6-3 6-1 |
| WD QF | Jensen/Alonso De Villa def. Arruabarrena/Bidahorria 6-3 6-1 |
| MD Q-R32 | Miñano Ortinez/Mena def. Schoonus/Meijer 6-0 6-2 |
| MD R32 | Di Nenno/Augsburger def. Rico/Sager 4-6 6-7 |
| WD R32 | Martinez Gomez/Rodriguez def. Las Heras/Arellano Navarro 6-1 6-2 |
| MD R64 | Fernandez Lancha/Cepero def. Montiel Caruso/Belluati 6-1 2-6 6-4 |
| MD R32 | Jofre/Arroyo def. Quilez/Sans 6-1 7-6 |
| MD SF | Coello/Tapia def. Nieto/Yanguas 4-6 6-1 6-0 |
| MD R32 | Marques Berdonce/Sintes Villalonga def. Cardona/Garrido 6-2 3-6 6-4 |
| MD R32 | Aguirre/Chozas def. Rico/Sánchez Chamero 0-6 1-6 |
| MD R64 | Goenaga/Hernandez Quesada def. Fernandez/Garcia 6-2 6-2 |
| MD F | Coello/Tapia def. Chingotto/Galan 6-3 7-6 |
| MD R32 | Chingotto/Galan def. Dominguez/Martinez 1-6 3-6 |
| MD R64 | Mouriño/Valenzuela def. Van Opstal/Nolten 1-6 5-7 |
| MD R32 | Leal/Bergamini def. Rubio/Ruiz 4-6 6-2 6-1 |
| MD R64 | Gutierrez/Valdes def. Garcia Garcia/Gonzalez 3-6 4-6 |
| MD R64 | Rico/Sánchez Chamero def. Del Castillo/Zapata 4-6 5-7 |
| MD Q-R32 | Santigosa Sastre/Axelsson def. Sanchez Vicente/Cordoba 3-6 4-6 |
| MD Q-R32 | Marques Berdonce/Sintes Villalonga def. Romera Barcelo/Vasquez 6-4 7-6 |
| WD Q-R16 | Mesa Salazar/Ruiz Soto def. Betz/Castillo Velarde 6-4 6-1 |
| WD Q-QF | Las Heras/Arellano Navarro def. Lobo/Navarro lopez-Barajas 4-6 6-4 7-6 |
| WD Q-QF | Mesa Salazar/Ruiz Soto def. Ortiz Gasco/Dal Pozzo 6-3 6-4 |
| MD Q-R32 | Graziotti/Iacovino def. Medina Murphy/Chiostri 6-7 2-6 |
| MD Q-R32 | Abbate/Cassetta def. Groen/Groen 2-6 4-6 |
| MD Q-R32 | Olsson/Insa Sotillo def. Melendez Amaya/Melendez Amaya 3-6 6-2 6-4 |
| WD Q-R16 | Las Heras/Arellano Navarro def. Piltcher/Valenzuela 6-0 3-6 7-6 |
| MD Q-R16 | Gutierrez/Nuñez def. Olsson/Insa Sotillo 7-6 6-4 |
| MD Q-R32 | Rodriguez Martinez/Rubini def. Aliaga/Gonzalez Blanco 2-6 3-6 |
| MD Q-R32 | Arnaldos Serrano/Mendez def. Figuerola Santiago/Trillas Garcia 6-7 2-6 |
| WD Q-R16 | Lobo/Navarro lopez-Barajas def. Araus Lopez/Fito Fernandez 5-7 2-6 |
| MD Q-R32 | Gutierrez/Nuñez def. Ortega/Huete Hernandez 4-6 3-6 |
| MD Q-R32 | Quilez/Sans def. Aragon Herrera/Arija Ochoa De Alda 7-6 7-6 |
| MD Q-R16 | Santigosa Sastre/Axelsson def. Geens/Jerez Carnero 6-3 3-6 2-6 |
| WD Q-R16 | Ortiz Gasco/Dal Pozzo def. Casali/Parmigiani 5-7 2-6 |
| WD Q-QF | Martinez Fortun/Montes Cabruja def. Godallier/Marchetti 4-6 7-6 3-6 |
| MD Q-R16 | Rico/Sánchez Chamero def. Jensen Sirvent/Dal Bianco 7-6 4-6 6-1 |
| MD SF | Chingotto/Galan def. Stupaczuk/Lebron 3-6 5-7 |
| MD R32 | Guerrero/Gonzalez def. Fernandez Lancha/Cepero 6-7 4-6 |
| MD Q-R32 | Rico/Sánchez Chamero def. Gil/Moyano 6-7 6-2 6-4 |
| MD R16 | Coello/Tapia def. Aguirre/Chozas 6-3 6-0 |